A combined conductivity and DFT study of protons in PbZrO3 and alkaline earth zirconate perovskites
Artikel i vetenskaplig tidskrift, 2010

The electrical properties of nominally undoped and 4 mol% Y-doped PbZrO3 have been investigated by AC conductivity measurements and impedance spectroscopy under various p(H2)O and p(O2) at high temperatures. The results indicate that the defect structures are dominated by acceptors (Y dopant and/or Pb vacancies formed during synthesis). In dry atmosphere and at high temperatures, the acceptors are compensated by oxygen vacancies. These are hydrated and replaced by protonic defects (hydroxide ions on oxide ion sites) at higher p(H2)o and lower temperatures. In oxidizing atmospheres, a minority concentration of electron holes dominates the conductivity. At lower temperatures and in wet atmosphere, a significant protonic conductivity contribution is also observed. Based on p(O2) and p(H2)o isotherms, a model for incorporation of protonic defects has been applied, and the standard enthalpy of hydration of oxygen vacancies in undoped PbZrO3 has been determined (-1.07 +/- 0.13 eV). The measured total conductivities are influenced by high grain boundary resistance. Hence, the enthalpy is at the present stage assigned to the polycrystalline ceramic material as such. Rough estimates of bulk proton mobility in Y-doped PbZrO3 yield u(H)(0)+ = 17 cm(2)K/Vs and Delta H-m,H(+) = 0.93 eV. A complementary DFT study of the hydration thermodynamics of PbZrO3 and the alkaline earth zirconate perovskites AZrO(3) (A = Ca, Sr, Ba) is also reported. The experimental and theoretical hydration enthalpies are compared with those of other ABO(3) perovskites. Correlations between the hydration thermodynamics and other properties of the materials are discussed. (C) 2009 Elsevier B.V. All rights reserved.

NEUTRON-DIFFRACTION

ELECTRICAL-CONDUCTIVITY

LEAD-ZIRCONATE

Defects

PbZrO3

CAPACITORS

Hydration

TITANATE

OXIDES

MOLECULAR-DYNAMICS

STABILITY

SrZrO3

BaZrO3

Proton mobility

HYDROGEN

CaZrO3

Conductivity

Thermodynamics

Proton

CAZRO3

DFT

Författare

T. S. Bjorheim

Universitetet i Oslo

A. Kuwabara

Japan Fine Ceramics Center

Istaq Ahmed

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

R. Haugsrud

Universitetet i Oslo

S. Stolen

Universitetet i Oslo

T. Norby

Universitetet i Oslo

Solid State Ionics

0167-2738 (ISSN)

Vol. 181 130-137

Ämneskategorier

Fysik

Kemi

DOI

10.1016/j.ssi.2009.04.013