Structural and Vibrational Properties of Diglyme and Longer Glymes
Artikel i vetenskaplig tidskrift, 2010
The conformational states of diglyme in both the solid and liquid states have been determined by an integrated use of both IR and Raman spectroscopy together with ab initio/density functional theory (DFT) calculations. Using knowledge from diglyme also made possible the study of the conformational state of longer glymes, including a quantitative study of the D-LAM mode. We hereby unambiguously can assign the (tgt)(n) conformational state to all glymes and PEO in the solid state.
complexes
liquid-state
ft raman-spectroscopy
ionic association
oxide)
chain poly(oxyethylene) c1e3c1
poly(ethylene
spectra
conformational properties
ab-initio
molecular-structure
Författare
Patrik Johansson
Chalmers, Teknisk fysik, Kondenserade materiens fysik
J. Grondin
Institut des Sciences Moleculaires, Talence
Jean-Claude Lassegues
Institut des Sciences Moleculaires, Talence
Journal of Physical Chemistry A
1089-5639 (ISSN) 1520-5215 (eISSN)
Vol. 114 39 10700-10705Ämneskategorier
Fysik
DOI
10.1021/jp105437d