Structural and Vibrational Properties of Diglyme and Longer Glymes
Artikel i vetenskaplig tidskrift, 2010

The conformational states of diglyme in both the solid and liquid states have been determined by an integrated use of both IR and Raman spectroscopy together with ab initio/density functional theory (DFT) calculations. Using knowledge from diglyme also made possible the study of the conformational state of longer glymes, including a quantitative study of the D-LAM mode. We hereby unambiguously can assign the (tgt)(n) conformational state to all glymes and PEO in the solid state.

complexes

liquid-state

ft raman-spectroscopy

ionic association

oxide)

chain poly(oxyethylene) c1e3c1

poly(ethylene

spectra

conformational properties

ab-initio

molecular-structure

Författare

Patrik Johansson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

J. Grondin

Institut des Sciences Moleculaires, Talence

Jean-Claude Lassegues

Institut des Sciences Moleculaires, Talence

Journal of Physical Chemistry A

1089-5639 (ISSN) 1520-5215 (eISSN)

Vol. 114 10700-10705

Ämneskategorier

Fysik

DOI

10.1021/jp105437d