Application of combined neutron diffraction and impedance spectroscopy for in-situ structure and conductivity studies of La2Mo2O9
Artikel i vetenskaplig tidskrift, 2011

In-situ neutron diffraction combined with AC impedance spectroscopy was applied successfully to investigate the correlation between crystal structure and electrical properties of the La2Mo2O9 oxide ion conducting electrolyte material. Neutron diffraction patterns were collected as a function of temperature while the AC impedance spectra were recorded simultaneously using a modified sample environment to monitor the conductivity change of the sample. A close relationship between unit cell parameters and the bulk conductivity was observed, confirming that the oxygen transport is dependent on the lattice structure. With the transition from the low temperature alpha to the high temperature beta phase, expansion of the crystal structure makes more space available for oxygen transport, leading to a dramatic increase of the ionic conductivity. The successful application of this technique provides a new method to simultaneously investigate crystal structure and electrical properties in electro-ceramics in the future.

lamox

Impedance spectroscopy

crystal-structure

oxide-ion conductors

In-situ

Neutron diffraction

Electrolyte

La2Mo2O9

Författare

J. J. Liu

Imperial College London

S. Hull

ISIS Facility

Istaq Ahmed

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

S. J. Skinner

Imperial College London

Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

0168-583X (ISSN)

Vol. 269 539-543

Ämneskategorier

Fysik

DOI

10.1016/j.nimb.2011.01.004