Molecular Implementation of Sequential and Reversible Logic Through Photochromic Energy Transfer Switching
Artikel i vetenskaplig tidskrift, 2011

Photochromic spiropyrans modified with fluorophores were investigated as molecular platforms for the achievement of fluorescence switching through modulation of energy transfer. The dyads were designed in such a way that energy transfer is only observed for the open forms of the photochrome (merocyanine and protonated merocyanine), whereas the closed spiropyran is inactive as an energy acceptor. This was made possible through a deliberate choice of fluorophores (4-amino-1,8-naphthalimide, dansyl, and perylene) that produce zero spectral overlap with the spiro form and considerable overlap for the merocyanine forms. From the Förster theory, energy transfer is predicted to be highly efficient and in some cases of 100 % efficiency. The combined switching by photonic (light of λ>530 nm) and chemical (base) inputs enabled the creation of a sequential logic device, which is the basic element of a keypad lock. Furthermore, in combination with an anthracene-based acidochromic fluorescence switch, a reversible logic device was designed. This enables the unambiguous coding of different input combinations through multicolour fluorescence signalling. All devices can be conveniently reset to their initial states and repeatedly cycled.

spiro compounds

logic gates



energy transfer


Patricia Remón Ruiz

Universidad de Huelva

Martin Hammarson

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Shiming Li

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Axel Kahnt

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

U. Pischel

Universidad de Huelva

Joakim Andreasson

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Chemistry - A European Journal

0947-6539 (ISSN) 1521-3765 (eISSN)

Vol. 17 6492-6500


Nanovetenskap och nanoteknik


Fysikalisk kemi