Efficiency enhancement in dye sensitized solar cells using gel polymer electrolytes based on a tetrahexylammonium iodide and MgI2 binary iodide system
Artikel i vetenskaplig tidskrift, 2012

Quasi-solid-state dye-sensitized solar cells have drawn the attention of scientists and technologists as a potential candidate to supplement future energy needs. The conduction of iodide ions in quasi-solid-state polymer electrolytes and the performance of dye sensitized solar cells containing such electrolytes can be enhanced by incorporating iodides having appropriate cations. Gel-type electrolytes, based on PAN host polymers and mixture of salts tetrahexylammonium iodide (Hex(4)N(+)I(-)) and MgI2, were prepared by incorporating ethylene carbonate and propylene carbonate as plasticizers. The salt composition in the binary mixture was varied in order to optimize the performance of solar cells. The electrolyte containing 120% Hex(4)N(+)I(-) with respect to weight of PAN and without MgI2 showed the highest conductivity out of the compositions studied, 2.5 x 10(-3) S cm(-1) at 25 degrees C, and a glass transition at -102.4 degrees C. However, the electrolyte containing 100% Hex(4)N(+)I(-) and 20% MgI2 showed the best solar cell performance highlighting the influence of the cation on the performance of the cell. The predominantly ionic behaviour of the electrolytes was established from the dc polarization data and all the electrolytes exhibit iodide ion transport. Seven different solar cells were fabricated employing different electrolyte compositions. The best cell using the electrolyte with 100% Hex(4)N(+)I(-) and 20% MgI2 with respect to PAN weight showed 3.5% energy conversion efficiency and 8.6 mA cm(-2) short circuit current density.

films

peo

composite

conversion

ionic-conductivity

lithium

nanocrystalline tio2

layer

photovoltaic performance

complex

Författare

T M W J Bandara

Chalmers, Teknisk fysik, Fasta tillståndets fysik

M.A.K.L. Dissanayake

National Institute of Fundamental Studies

W. Jayasundara

University of Peradeniya

Ingvar Albinsson

Göteborgs universitet

Bengt-Erik Mellander

Chalmers, Teknisk fysik, Fasta tillståndets fysik

Physical Chemistry Chemical Physics

1463-9076 (ISSN) 1463-9084 (eISSN)

Vol. 14 24 8620-8627

Drivkrafter

Hållbar utveckling

Ämneskategorier

Fysik

Kemi

Styrkeområden

Energi

Materialvetenskap

DOI

10.1039/c2cp24139k