X-ray Transient Absorption and Picosecond IR Spectroscopy of Fulvalene(tetracarbonyl)diruthenium on Photoexcitation
Artikel i vetenskaplig tidskrift, 2012

Caught in the light: The fulvalene diruthenium complex shown on the left side of the picture captures sun light, causing initial Ru–Ru bond rupture to furnish a long-lived triplet biradical of syn configuration. This species requires thermal activation to reach a crossing point (middle) into the singlet manifold on route to its thermal storage isomer on the right through the anti biradical.

ruthenium

isomerization

time-resolved spectroscopy

ab initio calculations

photochemistry

Författare

Michael R. Harpham

Argonne National Laboratory

Son C. Nguyen

University of California

Zongrui Hou

University of California

Jeffrey C. Grossman

Massachusetts Institute of Technology (MIT)

Charles B. Harris

University of California

Michael W. Mara

Northwestern University

Andrew B. Stickrath

Argonne National Laboratory

Yosuke Kanai

The University of North Carolina at Chapel Hill

Alexie M. Kolpak

Massachusetts Institute of Technology (MIT)

Donghwa Lee

The University of North Carolina at Chapel Hill

Di-Jia Liu

Argonne National Laboratory

Justin P. Lomont

University of California

Kasper Moth-Poulsen

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

N. Vinokurov

University of California

Lin X. Chen

Argonne National Laboratory

K. P. C. Vollhardt

University of California

Angewandte Chemie - International Edition

1433-7851 (ISSN) 1521-3773 (eISSN)

Vol. 51 7692-7696

Ämneskategorier

Oorganisk kemi

Fysikalisk kemi

Styrkeområden

Energi

Materialvetenskap

DOI

10.1002/anie.201202952