Bridging nitrile groups in a metal-organic framework
Artikel i vetenskaplig tidskrift, 2012

This article describes two coordination polymers based on sodium and nickel triflates, respectively, and the linker adiponitrile (1,4-butanedinitrile). Sodium triflate forms a coordination network with adiponitrile, where the nitriles bridge the sodium ions, a rare coordination mode for a nitrile. Crystal structures of alkali metal complexes of linear aliphatic dinitriles have not been reported previously. With nickel triflate, a cationic 1-D coordination polymer results upon coordination of adiponitrile.

ligand

coordination

chloride

Coordination polymer

acetonitrile

molecular-structure

Dinitrile

MOF

crystal-structure

complex

Författare

Anders Lennartsson

Chalmers, Kemi- och bioteknik, Polymerteknologi

C. J. McKenzie

University of Southern Denmark

Journal of Coordination Chemistry

0095-8972 (ISSN)

Vol. 65 23 4194-4202

Ämneskategorier

Kemi

DOI

10.1080/00958972.2012.734610

Mer information

Senast uppdaterat

2018-09-06