Influence of Different Pretreatment Methods on Biomass Gasification and Production of Fischer-tropsch Crude Integrated with a Pulp and Paper Mill
Artikel i vetenskaplig tidskrift, 2013
In this paper, the influence on the system performance of different biomass pretreatment methods before
gasification and subsequent production of Fischer-Tropsch crude is considered. Entrained flow gasification
at high pressure is a well proven technology for coal as feedstock with the benefit of producing a
practically tar free raw gas with a close to complete carbon conversion. The short residence time in this
type of gasifier requires a fuel, which is relatively dry and has a small particle size, to be pressurized from
ambient conditions up to 20-50 bar. The small particle size can be acquired by grinding but this is highly
energy intensive and feeding is challenging. Torrefaction is a thermal pretreatment method carried out at
around 300 °C which makes the biomass easier to grind, thus requiring less electricity, and makes the
material less fibrous, while on the other hand requiring heat for the process. Pyrolysis is a process carried
out at around 500 °C which lets the biomass decompose into a gaseous, a liquid and a solid part. The
solid part can be grinded and fed into the gasifier together with the liquid and gaseous phases. This will
further facilitate the feeding but with a further increased heat demand compared to torrefaction. The
different pretreatment methods and their impact on the overall biorefinery energy system have been
studied and evaluated using process integration methodology. The results show that the excess heat from
an FT process with a biomass input of 300 MW(HHV) can replace the solid fuel boiler in a large chemical pulp
and paper mill. With the preconditions given for this study, thermal pretreatment of the biomass can be
beneficial in terms of system thermal efficiency.
energy efficiency
Fischer-Tropsch
pretreatment
biomass gasification
pyrolysis
process integration
torrefaction