Highly enantioselective hydrogenation and transfer hydrogenation of cycloalkyl and heterocyclic ketones catalysed by an iridium complex of a tridentate phosphine-diamine ligand
Artikel i vetenskaplig tidskrift, 2013

Ir complexes of chiral phosphine-diamine ligands catalyse the hydrogenation and transfer hydrogenation of aryl-piperidin-4-ylmethanones, and ketones bearing both an aryl group and secondary alkyl substituent with up to 98% e.e., and with substrate to catalyst ratios of up to 4000.


J. A. Fuentes

University of St Andrews

I. Carpenter

University of St Andrews

Nina Kann

Chalmers, Kemi- och bioteknik, Organisk kemi

M. L. Clarke

University of St Andrews

Chemical Communications

1359-7345 (ISSN)

Vol. 49 87 10245-10247