Influence of temperature on ionic liquid-based gel polymer electrolyte prepared by electrospun fibrous membrane
Artikel i vetenskaplig tidskrift, 2014

Ionic liquid gel polymer electrolytes (ILPEs) based on electrospun P(VdF-HFP) membrane were prepared by incorporating RTILs, BMImTESI or BMImBF(4). A suitable BMIm cation based ionic liquid with lithium salt and influence of temperature on electrochemical performance was investigated. The BMImTFSI-based polymer electrolyte with LiTFSI salt showed better electrochemical properties and the properties increase with increasing the operation temperature to 40 degrees C, to 140 mAh g(-1) discharge capacity at 1 C-rate. However, after 40 degrees C the properties remained the same even when the temperature was increased at high current density.

BIS(TRIFLUOROMETHANESULFONYL)IMIDE

PAN

Gel polymer electrolyte

COMPOSITE

LITHIUM BATTERIES

Electrospun membrane

TRANSPORT-PROPERTIES

Electrochemical performance

LIFEPO4 CATHODE

Ion coordination

CONDUCTIVITY

POLY(VINYLIDENE FLUORIDE-CO-HEXAFLUOROPROPYLENE)

Ionic liquid electrolyte

SOLID ELECTROLYTES

ELECTROCHEMICAL PROPERTIES

Författare

J. K. Kim

Chalmers

Ulsan National Institute of Science and Technology (UNIST)

J. H. Ahn

Gyeongsang National University

Per Jacobsson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Electrochimica Acta

0013-4686 (ISSN)

Vol. 116 321-325

Ämneskategorier

Fysik

DOI

10.1016/j.electacta.2013.11.061

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Senast uppdaterat

2018-09-10