One-pot synthesis of TBTA-functionalized coordinating polymers
Artikel i vetenskaplig tidskrift, 2014

A one-pot method for the functionalization of polyvinylbenzyl chloride with a tris-(benzyltriazolylmethyl)amine (TBTA) ligand via the copper-catalyzed azide–alkyne cycloaddition reaction (CuAAC) is reported, where the ligand is constructed simultaneously with its attachment to the polymer backbone. A hydrophobic TBTA polymer as well as co-polymers containing TBTA ligands were also prepared to demonstrate the possibility of tailoring the properties of the polymers. The polymers were characterized with FT-IR and NMR spectroscopy, elemental analysis, contact angle measurement, differential scanning calorimetry and thermal gravimetric analysis. The metal coordinating properties of films prepared from the polymers was also demonstrated using X-ray photoelectron spectroscopy and their structures inspected by scanning electron microscopy.

Triazole

Coordinating polymer

Copper

Polyvinylbenzyl chloride

Cycloaddition

Författare

Alireza Movahedi

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

Kasper Moth-Poulsen

Chalmers, Kemi- och bioteknik, Polymerteknologi

Johnas Eklöf

Chalmers, Kemi- och bioteknik, Polymerteknologi

Magnus Nydén

Chalmers University of Technology

University of South Australia

Nina Kann

Chalmers, Kemi- och bioteknik, Organisk kemi

Reactive and Functional Polymers

1381-5148 (ISSN)

Vol. 82 1-8

Ämneskategorier

Polymerkemi

Kemi

Organisk kemi

Styrkeområden

Energi

Materialvetenskap

DOI

10.1016/j.reactfunctpolym.2014.05.008