Structures of ionic liquid-water mixtures investigated by IR and NMR spectroscopy
Artikel i vetenskaplig tidskrift, 2014

Imidazolium-based ionic liquids having different anions 1-butyl-3-methylimidazolium ([BMIM] X: X = Cl-, Br-, I-, and BF4-) and their aqueous mixtures were investigated by IR absorption and proton NMR spectroscopy. The IR spectra of these ionic liquids in the CHx stretching region differed substantially, especially for C-H bonds in the imidazolium ring, and the NMR chemical shifts of protons in the imidazolium ring also varied markedly for ILs having different anions. Upon the introduction of water to screen the electrostatic forces and separate the ions, both IR and NMR spectra of [BMIM] X (X = Cl-, Br-, I-) showed significant changes, while those of [BMIM] BF4 did not change appreciably. H-D isotopic exchange rates of C(2)-H in [BMIM] X-D2O mixtures exhibited an order: C(2)-H center dot center dot center dot Cl > C(2)-H center dot center dot center dot Br > C(2)-H center dot center dot center dot I, while the C(2)-H of [BMIM] BF4 was not deuterated at all. These experimental findings, supported by DFT calculations, lead to the microscopic bulk configurations in which the anions and the protons of the cations in the halide ionic liquids have specific, hydrogen-bond type of interaction, while the BF(4)(-)anion does not participate in the specific interaction, but interacts less specifically by positioning itself more above the ring plane of the imidazolium cation. This structural change dictated by the anion type will work as a key element to build the structure-property relationship of ionic liquids.

Författare

S. Cha

Sogang University

M. Ao

Sogang University

W. Sung

Sogang University

B. Moon

Sogang University

Bodil Ahlström

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Patrik Johansson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Y. Ouchi

Tokyo Institute of Technology

D. Kim

Sogang University

Physical Chemistry Chemical Physics

1463-9076 (ISSN) 1463-9084 (eISSN)

Vol. 16 9591-9601

Ämneskategorier

Fysikalisk kemi

Infrastruktur

C3SE (Chalmers Centre for Computational Science and Engineering)

Styrkeområden

Materialvetenskap

DOI

10.1039/c4cp00589a