Ash Properties of Ilmenite Used as Bed Material for Combustion of Biomass in a Circulating Fluidized Bed Boiler
Artikel i vetenskaplig tidskrift, 2014

Both agglomeration of bed material and corrosion of heat transfer equipment are issues related to combustion of biomass in a fluidized bed boiler. The biomass-ash component potassium is considered a major contributor for both phenomena. In this study, the conventionally used bed material, silica sand, was replaced with up to 40 wt % by the natural ore ilmenite in Chalmers 12 MWth circulating fluidized bed (CFB) boiler. In this study the purpose was to evaluate the physical and chemical changes ilmenite undergoes during this process. Close observations revealed that ilmenite underwent segregation of iron to the surfaces and an enrichment of titanium in the particle core. The ash formed a calcium-rich double layer on the particle, surrounding the iron layer. A diffusion of potassium into the particle core was also seen which led to the formation of KTi8O16. In addition to evaluating how ash components interact with the material, the ilmenite was leached and investigated as a possible potassium capturer. Leaching experiments on the used ilmenite showed that calcium and potassium were leachable to a very limited degree, namely, to less than 0.2 and 1 wt %, respectively, of the total content. The diffusion of potassium into the core of the particle could reduce both agglomeration and corrosion issues and could thereby be of great value for the improvement of the resistance of the bed material agglomeration in the fluidized bed boiler.

Författare

Angelica Corcoran

Chalmers, Energi och miljö, Energiteknik

Jelena Maric

Chalmers, Energi och miljö, Energiteknik

Fredrik Lind

Chalmers, Energi och miljö, Energiteknik

Henrik Thunman

Chalmers, Energi och miljö, Energiteknik

Pavleta Knutsson

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

Martin Seemann

Chalmers, Energi och miljö, Energiteknik

Energy & Fuels

0887-0624 (ISSN) 1520-5029 (eISSN)

Vol. 28 12 7672-7679

Drivkrafter

Hållbar utveckling

Ämneskategorier

Energiteknik

Styrkeområden

Energi

DOI

10.1021/ef501810u