Extraordinary aluminum coordination in a novel homometallic double complex salt
Artikel i vetenskaplig tidskrift, 2015

We have characterized a novel aluminum-based homometallic double complex salt, incorporating discrete octa-coordinated cationic [Al(G3)(2)](3+) and hexa-coordinated anionic [Al(TfO)(4)(OH)(2)](3-) complexes (G3 = triglyme, TfO = trifluoromethanesulfonate). X-ray crystallography, Raman spectra, and DFT calculations demonstrate extraordinary weak Al3+ coordination in [Al(G3)(2)](3+).

Författare

Toshihiko Mandai

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Hyuma Masu

Chiba University

Patrik Johansson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Dalton Transactions

1477-9226 (ISSN) 1477-9234 (eISSN)

Vol. 44 11259-11263

Ämneskategorier

Den kondenserade materiens fysik

DOI

10.1039/c5dt01220a

PubMed

26024493