Synthesis of carbon nanotube films by thermal CVD in the presence of supported catalyst particles. Part I: The silicon substrate/nanotube film interface
Artikel i övriga tidskrifter, 2004

The interface between the silicon substrate and a carbon nanotube film grown by thermal CVD with acetylene (C2H2) and hydrogen at 750 or 900 °C has been characterized by high resolution and analytical transmission electron microscopy, including electron spectroscopic imaging. Silicon (0 0 2) substrates coated with a thin (2.8 nm) iron film were heat treated in the CVD furnace at the deposition temperature in a mixture of flowing argon and hydrogen whereby nanosized particles of (Fe,Si)3O4 formed. These particles were reduced to catalytic iron silicides with the α–(Fe, Si), α2–Fe2Si and α1–Fe2Si structures during CVD at 900 °C, and multi-wall carbon nanotubes grew from supported particles via a base-growth mechanism. A limited number of intermediate iron carbides, hexagonal and orthorhombic Fe7C3, were also present on the substrate surface after CVD at 900 °C. The reduction of the preformed (Fe, Si)3O4 particles during thermal CVD at 750 °C was accompanied by disintegration leading to the formation of a number of smaller (<5 and up to 10 nm) iron and silicon containing particles. It is believed that the formation of these small particles is a prerequisite for the growth of aligned multi-wall carbon nanotube films.

Författare

Yiming Yao

Chalmers, Institutionen för experimentell fysik

Lena Falk

Chalmers, Institutionen för experimentell fysik, Mikroskopi och mikroanalys

Raluca Elena Morjan

Chalmers, Institutionen för experimentell fysik, Atomfysik

O.A. Nerushev

Chalmers, Institutionen för tillämpad fysik

Eleanor E.B. Campbell

Chalmers, Institutionen för experimentell fysik, Atomfysik

Journal of Materials Science: Materials in Electronics

Vol. 15 8 533-543

Styrkeområden

Nanovetenskap och nanoteknik

Materialvetenskap

Ämneskategorier

Kemiska processer

Annan materialteknik

Annan elektroteknik och elektronik

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2017-10-07