A redetermination of cis-aquabis(glycinato-κ2N,O)copper(II)
Artikel i vetenskaplig tidskrift, 2004

The crystal structure of the title compound, [Cu(C2H4NO2)2(H2O)], reported by Freeman et al. [(1964). Acta Cryst. 17, 1463-1470], has been reinvestigated and its absolute configuration established by anomalous dispersion effects. The origin of chirality in the crystalline state of this compound is the formation of right-handed helices from a CuII coordination network self-resolved into a pure enantiomeric phase.

X-ray crystal structure

absolute configuration

Författare

Barbara Casari

Amir Mahmoudkhani

Vratislav Langer

Chalmers, Institutionen för oorganisk miljökemi

Acta Crystallographica Section E: Structure Reports Online

1600-5368 (ISSN)

Vol. E60 m1949-m1951

Ämneskategorier

Kemi