Tuning the photochemical properties of the fulvalene-tetracarbonyl-diruthenium system
Artikel i vetenskaplig tidskrift, 2016

In a Molecular Solar-Thermal Energy Storage (MOST) system, solar energy is converted to chemical energy using a compound that undergoes reversible endothermic photoisomerization. The high-energy photoisomer can later be converted back to the parent compound and the excess energy is released as heat. One of the most studied MOST systems is based on fulvalene-tetracarbonyl-diruthenium, and this paper demonstrates, for the first time, the possibility to tune the photochemical properties of this system by positive steric hindrance working on the fulvalene unit.

Författare

Anders Lennartsson

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

Angelica Lundin

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

Karl Börjesson

Göteborgs universitet

Victor Gray

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

Kasper Moth-Poulsen

Chalmers, Kemi och kemiteknik, Tillämpad kemi, Polymerteknologi

Dalton Transactions

1477-9226 (ISSN) 1477-9234 (eISSN)

Vol. 45 8740-8744

Ämneskategorier

Polymerkemi

Infrastruktur

Chalmers infrastruktur för masspektrometri

C3SE (Chalmers Centre for Computational Science and Engineering)

Chalmers materialanalyslaboratorium

Styrkeområden

Energi

Materialvetenskap

DOI

10.1039/c6dt01343k

PubMed

27109432