Elements of modeling nanoparticle growth: Surface thermodynamics and dispersive interactions
Licentiatavhandling, 2017

Metal nanoparticles have in recent decades been the subject of intense research owing to their wide range of size and shape-dependent properties, which makes them interesting candidates for a variety of applications. Gold nanorods represent a particularly intriguing type of particle due to their tunable plasmonic properties. To benefit from these features, access to a large supply of high-quality, monodisperse nanorods is required, but has yet to be realized. The most facile route to obtaining nanorods is through seeded-mediated growth, a family of wet-chemical synthesis protocols. While such protocols have the potential of delivering high quantities of rods with finely tuned properties, progress is being hampered by a lack of theoretical understanding regarding the growth mechanism. The aim of this thesis is to lay the foundation for a comprehensive picture of the gold nanorod growth process. In particular, the role of the CTAB surfactant layer covering the nanorod surfaces is investigated. The discussion is based on first-principles density functional theory calculations, molecular dynamics simulations carried out in our research group, and a critical review of ideas found in literature. A framework for explaining experimental observations and predicting the outcome of synthesis processes as a function of their parameters is presented based on the surface phase diagram of CTAB. A key feature of the phase diagram, in addition to the conventional bilayer structure that is often assumed, is the existence of cylindral and spherical micelles. These micelles expose the underlying gold surface to incoming gold ions that fuel the growth. The importance of dispersive interactions in understanding transitions between the different phases is emphasized. Furthermore, different models for the anistropic growth are reviewed within the newly established framework, and are complemented by a discussion of the impact of the seed particle structure.

density functional theory

growth mechanism

gold nanorods

dispersive interactions

molecular dynamics

van der Waals forces

thermodynamics

CTAB

anisotropic nanoparticles

modeling

surface phase diagram

PJ-salen, Fysikgården 2, Göteborg
Opponent: Patrik Johansson, Chalmers University of Technology, Sweden

Författare

Joakim Löfgren

Chalmers, Fysik, Material- och ytteori

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Ämneskategorier

Oorganisk kemi

Fysikalisk kemi

Den kondenserade materiens fysik

Styrkeområden

Transport

Utgivare

Chalmers tekniska högskola

PJ-salen, Fysikgården 2, Göteborg

Opponent: Patrik Johansson, Chalmers University of Technology, Sweden