Bis(cyanamidonitrato-κN)[tris(3,5-dimethylpyrazole)copper(II)
Artikel i vetenskaplig tidskrift, 2003

The title compound, [Cu(CN3O2)2(C5H8N2)3], is the first example of a pentacoordinated 3d-central atom involving the cyanamidonitrate ligand. The crystal structure is formed by neutral molecues stabilized by a three-dimensional network consisting of one intramolecular and three intermolecular hydrogen bonds. The Cu atom is pentacoordinated by three N-donor atoms from 3,5-dimethylpyrazole neutral ligands and two N-donor atoms from cyanamidonitrate anions.

cyanamidonitrate ligand

coordination

X-ray diffraction

Författare

Jesus Garcia Diaz

Jozef Kozisek

Vratislav Langer

Chalmers, Institutionen för oorganisk miljökemi

Acta Crystallographica Section E: Structure Reports Online

1600-5368 (ISSN)

Vol. E59 m241-m243

Ämneskategorier

Kemi