Structure of Filter Cakes during the Electroassisted Filtration of Microfibrillated Cellulose
Artikel i vetenskaplig tidskrift, 2022

Microfibrillated cellulose (MFC) is a biobased material with unique properties that can be used in a multitude of applications. Water removal from the dilute product streams is, however, challenging and hinders its commercial attractiveness. One possible method of improving dewatering is the use of electroassisted filtration, in which an electric field is applied across part of the filter chamber. In this work, a bench-scale dead-end filter press, modified to allow for electroassisted filtration, was used to dewater a suspension of MFC produced via 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO)-mediated oxidation. A filter cake was produced with a channeled structure related to the design of the anode mesh, indicating that the cellulose microfibrils were aligned in the direction of the electric field. This was investigated, qualitatively and quantitively, using scanning electron microscopy and wide-angle X-ray scattering, which showed a preferred orientation on a microscopic level but only a partial orientation on a molecular level (fc between 0.49 and 0.57). The influence of the density of the anode mesh, in terms of the structure/permeability of the filter cake and dewatering rate, was also evaluated using two different anode mesh densities (5 × 5 and 10 × 10 mm). It was not, however, found to have any major impact on the dewatering rate.

Författare

Anna Lidén

Chalmers, Kemi och kemiteknik, Kemiteknik

Polina Naidjonoka

Chalmers, Fysik, Materialfysik

Nabin Kumar Karna

Wallenberg Wood Science Center (WWSC)

Chalmers, Kemi och kemiteknik, Kemiteknik

Hans Theliander

Chalmers, Kemi och kemiteknik, Kemiteknik

Wallenberg Wood Science Center (WWSC)

Industrial & Engineering Chemistry Research

0888-5885 (ISSN) 1520-5045 (eISSN)

Vol. 61 43 16247-16256

Ämneskategorier

Polymerteknologi

Textil-, gummi- och polymermaterial

Materialkemi

Infrastruktur

Chalmers materialanalyslaboratorium

DOI

10.1021/acs.iecr.2c03216

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Senast uppdaterat

2024-03-07