On the effect of preoxidation of nickel alloy X-750
Paper i proceeding, 2018

Nickel Alloy X-750 is a Ni-Cr–Fe alloy with good corrosion properties and high strength at elevated temperature. It is commonly used for spacer grids in Boiling Water Reactors (BWR). In this environment, the material can suffer from significant corrosion, leading to weight loss by metal dissolution. To further improve the characteristics of this material, a process called preoxidation is often performed. This results in the formation of strengthening γ’-Ni 3 (Ti, Al) precipitates and a thin oxide on the surface. In this paper, preoxidized and non-preoxidized specimens are compared with respect to their oxidation properties. We report about microstructural studies made on specimens exposed in simulated BWR environment for 24 h and 840 h. Electron microscopy techniques have been used to investigate the oxide microstructures. A comparison between these specimens shows the complexity of the corrosion process and the impact of preoxidation. Preoxidized specimens show thinner and more homogenous oxides than non-preoxidized ones. They lose less mass and build thinner oxides. The preoxidation layer consists of a bilayer oxide of NiFe 2 O 4 and Cr 2 O 3 that is preserved during the long exposure. NiFe 2 O 4 spinel crystals are present on the surface of all exposed specimens, a result of re-precipitation of dissolved metal ions.

High temperature water

NiFe2O4

Oxide formation

Nickel based alloys

BWR

X-750

Corrosion

Författare

Silvia Tuzi

Chalmers, Fysik, Materialens mikrostruktur

Kenneth Göransson

Westinghouse Electric Sweden AB

Fang Liu

Chalmers, Industri- och materialvetenskap, Material och tillverkning

Mattias Thuvander

Chalmers, Fysik, Materialens mikrostruktur

Krystyna Marta Stiller

Chalmers, Fysik, Materialens mikrostruktur

Minerals, Metals and Materials Series

2367-1181 (ISSN) 2367-1696 (eISSN)

Vol. Part F11 407-416

18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors
Portland, USA,

Ämneskategorier

Materialkemi

Annan materialteknik

Korrosionsteknik

DOI

10.1007/978-3-319-68454-3_32

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Senast uppdaterat

2018-04-04