α-Aminoalkyl Radical Addition to Maleimides via Electron Donor-Acceptor Complexes
Artikel i vetenskaplig tidskrift, 2018
A catalyst-free, photochemical oxidative annulation reaction between dialkylanilines and maleimides to generate tetrahydroquinolines is presented. The reaction is driven by the photochemical activity of an electron donor–acceptor (EDA) complex and has a broad substrate scope with the corresponding products isolated in good to excellent yields. Photochemical characterization of the EDA complex and a mechanistic rational is provided.
Författare
Chien-Wei Hsu
Chalmers, Kemi och kemiteknik
Henrik Sundén
Chalmers, Kemi och kemiteknik, Kemi och biokemi
Organic Letters
1523-7060 (ISSN) 1523-7052 (eISSN)
Vol. 20 7 2051-2054Drivkrafter
Hållbar utveckling
Styrkeområden
Nanovetenskap och nanoteknik
Fundament
Grundläggande vetenskaper
Ämneskategorier
Organisk kemi
DOI
10.1021/acs.orglett.8b00597