Simulating secondary organic aerosol from missing diesel-related intermediate-volatility organic compound emissions during the Clean Air for London (ClearfLo) campaign
Artikel i vetenskaplig tidskrift, 2016

We present high-resolution (5km × 5km) atmospheric chemical transport model (ACTM) simulations of the impact of newly estimated traffic-related emissions on secondary organic aerosol (SOA) formation over the UK for 2012. Our simulations include additional diesel-related intermediate-volatility organic compound (IVOC) emissions derived directly from comprehensive field measurements at an urban background site in London during the 2012 Clean Air for London (ClearfLo) campaign. Our IVOC emissions are added proportionally to VOC emissions, as opposed to proportionally to primary organic aerosol (POA) as has been done by previous ACTM studies seeking to simulate the effects of these missing emissions. Modelled concentrations are evaluated against hourly and daily measurements of organic aerosol (OA) components derived from aerosol mass spectrometer (AMS) measurements also made during the ClearfLo campaign at three sites in the London area. According to the model simulations, diesel-related IVOCs can explain on average  ∼ 30% of the annual SOA in and around London. Furthermore, the 90th percentile of modelled daily SOA concentrations for the whole year is 3.8µgm−3, constituting a notable addition to total particulate matter. More measurements of these precursors (currently not included in official emissions inventories) is recommended. During the period of concurrent measurements, SOA concentrations at the Detling rural background location east of London were greater than at the central London location. The model shows that this was caused by an intense pollution plume with a strong gradient of imported SOA passing over the rural location. This demonstrates the value of modelling for supporting the interpretation of measurements taken at different sites or for short durations.

Författare

Riinu Ots

Dominique E. Young

M. Vieno

Lu Xu

Rachel E. Dunmore

James D. Allan

Hugh Coe

Leah R. Williams

S. C. Herndon

Nga L. Ng

Jacqueline F. Hamilton

Robert Bergström

Göteborgs universitet, Institutionen för Kemi

SMHI

Chiara Di Marco

E. Nemitz

Ian A. Mackenzie

Jeroen J. P. Kuenen

David C. Green

S. Reis

M. R. Heal

Atmospheric Chemistry and Physics

1680-7316 (ISSN) 1680-7324 (eISSN)

Vol. 16 10 6453-6473

Drivkrafter

Hållbar utveckling

Styrkeområden

Transport

Ämneskategorier

Meteorologi och atmosfärforskning

Miljövetenskap

Fundament

Grundläggande vetenskaper

DOI

10.5194/acp-16-6453-2016

Mer information

Senast uppdaterat

2019-02-03