Ionic Liquids and Their Polymers in Lithium-Sulfur Batteries
Reviewartikel, 2019
Future optimized lithium-sulfur batteries may promise higher energy densities than the current standard. However, there are many barriers which hinder their commercialization. In this review we describe how ionic liquids (ILs) and their polymers are utilized in different components of the battery to address some of these issues. For example, IL-based electrolytes have the potential to reduce the solubility of polysulfides compared to conventional organic electrolytes. Polymerizing ILs directly on the surface of the Li-metal anode is suggested as an approach to protect the surface of this electrode. Finally, using poly(ionic liquids) (PILs) as binders for the cathode active material may increase the performance of the cathode as compared to polyvinylidene difluoride (PVdF) and could inhibit swelling-induced degradation. These results demonstrate the advantages of ILs and their polymers for improving the performance of Li−S batteries.
Lithium-sulfur batteries
electrolytes
ionic liquids
Li-metal anode
poly(ionic liquids)
Författare
Elinor Josef
Max-Planck-Gesellschaft
Yajing Yan
Chalmers, Fysik, Materialfysik
Marian Cristian Stan
Universität Münster
Julia Wellmann
Universität Münster
Alen Vizintin
Univerza V Ljubljani
Martin Winter
Universität Münster
Forschungszentrum Jülich
Patrik Johansson
Centre national de la recherche scientifique (CNRS)
Chalmers, Fysik, Materialfysik
R. Dominko
Centre national de la recherche scientifique (CNRS)
Univerza V Ljubljani
Ryan Guterman
Max-Planck-Gesellschaft
Israel Journal of Chemistry
0021-2148 (ISSN) 18695868 (eISSN)
Vol. 59 9 832-842Ämneskategorier
Materialkemi
Annan kemiteknik
Annan fysik
Annan kemi
DOI
10.1002/ijch.201800159