Improving Compositional Accuracy in APT Analysis of Carbides Using a Decreased Detection Efficiency
Artikel i vetenskaplig tidskrift, 2019

The composition of carbides in steel, measured by atom probe tomography, can be influenced by limitations in the ion detector system. When carbides are analyzed, many ions tend to field evaporate from the same region of the specimen during the same laser or voltage pulse. This results in a so-called multiple event, meaning that several ions impact the detector in close proximity both in time and space. Due to a finite detector dead-time not all ions can be detected, a phenomenon known as detector pile-up. The evaporation behavior of carbon is often different than the evaporation behavior of metals when analyzing alloy carbides, leading to preferential loss of carbon ions, and a measured carbon concentration below the expected value. This effect becomes stronger as the overall detection efficiency gets higher. Here, the detection efficiency was deliberately reduced by inserting a grid into the flight-path, which resulted in a higher and more correct carbon concentration, accompanied by an increase in the statistical uncertainty.

carbides

quantification

detection efficiency

atom probe tomography

multiple hits

Författare

Deodatta Shinde

Chalmers tekniska högskola

Mattias Thuvander

Chalmers, Fysik, Materialens mikrostruktur

Arbab Rehan

Uddeholms AB

Sebastian Ejnermark

Uddeholms AB

Krystyna Marta Stiller

Chalmers, Fysik, Materialens mikrostruktur

Microscopy and Microanalysis

1431-9276 (ISSN) 1435-8115 (eISSN)

Vol. 25 2 454-461

Ämneskategorier

Acceleratorfysik och instrumentering

Atom- och molekylfysik och optik

Fusion, plasma och rymdfysik

DOI

10.1017/S1431927619000424

PubMed

31018882

Mer information

Senast uppdaterat

2019-07-02