Revisiting Goodenough-Kanamori rules in a new series of double perovskites LaSr1-xCaxNiReO6
Artikel i vetenskaplig tidskrift, 2019

The magnetic ground states in highly ordered double perovskites LaSr1-xCaxNiReO6 (x = 0.0, 0.5, 1.0) are studied in view of the Goodenough-Kanamori rules of superexchange interactions in this paper. In LaSrNiReO6, Ni and Re sublattices are found to exhibit curious magnetic states separately, but no long range magnetic ordering is achieved. The magnetic transition at similar to 255 K is identified with the independent Re sublattice magnetic ordering. Interestingly, the sublattice interactions are tuned by modifying the Ni-O-Re bond angles through Ca doping. Upon Ca doping, the Ni and Re sublattices start to display a ferrimagnetically ordered state at low temperature. The neutron powder diffraction data reveals long range ferrimagnetic ordering of the Ni and Re magnetic sublattices along the crystallographic b-axis. The transition temperature of the ferrimagnetic phase increases monotonically with increasing Ca concentration.
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Scientific Reports

2045-2322 (ISSN) 20452322 (eISSN)

Vol. 9 Nummer/häfte 1 art. nr 18296

Kategorisering

Ämneskategorier (SSIF 2011)

Oorganisk kemi

Materialkemi

Den kondenserade materiens fysik

Identifikatorer

DOI

10.1038/s41598-019-54427-0

PubMed

31797876

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2023-05-26