CHALMEX FS-13 investigations for process implementation
Licentiatavhandling, 2020

From successive neutron absorption by uranium in nuclear reactors, transuranic elements such as neptunium, plutonium, americium and curium are produced. These elements are the main reason for the long-lived, highly radiotoxic and heat-producing nature of spent nuclear fuel. To reduce the strain on a final repository, the concept of partitioning and transmutation (P&T) has been developed. In P&T, the transuranic elements are partitioned from the nuclear fuel prior to final storage and transmuted into shorter-lived and far less radiotoxic elements. If the transmutation is facilitated in a nuclear reactor, as compared to in an accelerator driven system, further benefits include a more sustainable nuclear fuel cycle due to a reduced need for mining.

One partitioning option being developed is the Grouped ActiNide EXtraction (GANEX) process, which is a liquid-liquid extraction concept. In the Chalmers GANEX (CHALMEX) version, two extractants, tri-n-butyl phosphate (TBP) and 6,6’-bis-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-benzol-[1,2,4]-triazin-3-yl)-[2,2’]-bipyridine (CyMe4-BTBP) are combined for the direct separation of the transuranic elements from a spent nuclear fuel solution. The extractants are dissolved in phenyl trifluoromethyl sulfone (FS-13). The focus of the work presented in this thesis has been the optimisation and evaluation of the CHALMEX system for scaled up operations. Knowledge required for later process simulations, such as distribution ratios of all relevant elements over a range of acid concentrations, has been established. A fission product handling strategy using bimet and mannitol as masking agents has been suggested, although an efficient nickel and cadmium handling strategy is still required.

GANEX

Transmutation

Partitioning

CHALMEX

SolventExtraction

HB 1
Opponent: Frank Lewis, Northumbria University, United Kingdom

Författare

Thea Lyseid Authen

Chalmers, Kemi och kemiteknik, Energi och material, Kärnkemi

Authen T. L., Wilden, A., Halleröd, J., Schneider, D., Kreft, F., Modolo, G. and Ekberg, Ek. Batch Tests for optimisation of Solvent Composition and Process flexibility of the CHALMEX FS-13 Process.

Authen, T. L., Wilden, A., Schenider, D., Kreft, F., Modolo, G. and Ekberg, C. Batch flowsheet test of a GANEX-type process: the CHALMEX FS-13 process

GEN IV Integrated Oxide fuels recycling strategies (GENIORS)

Europeiska kommissionen (Horisont 2020), 2017-01-01 -- 2022-12-31.

Drivkrafter

Hållbar utveckling

Styrkeområden

Energi

Ämneskategorier

Kemiska processer

Kemiteknik

Energisystem

Utgivare

Chalmers tekniska högskola

HB 1

Opponent: Frank Lewis, Northumbria University, United Kingdom

Mer information

Skapat

2020-03-05