Review-Development of Huckel Type Anions: From Molecular Modeling to Industrial Commercialization. A Success Story
Reviewartikel, 2020
This paper reviews the battery electrolyte technologies involving Huckel-type salts as a major electrolyte component. The concept was initially proposed by M. Armand in 1995 and then explored by several research groups. In the present review studies on the optimization of the electrolyte composition starting from molecular modeling through enhancing the yield of the salt synthesis to structural characterization and electrochemical performance are described. Furthermore, the use of the optimized electrolytes in a variety of lithium-ion and post-lithium batteries is presented and discussed. Finally, the commercialization of the up to date technology by Arkema is discussed as well as the performance of the present Huckel anion based electrolytes as compared to other marketed electrolyte technologies.
Författare
M. Armand
CIC EnergiGUNE
Patrik Johansson
Chalmers, Fysik, Materialfysik
M. Bukowska
Politechnika Warszawska
P. Szczecinski
Politechnika Warszawska
L. Niedzicki
Centre national de la recherche scientifique (CNRS)
Politechnika Warszawska
M. Marcinek
Centre national de la recherche scientifique (CNRS)
Politechnika Warszawska
M. Dranka
Politechnika Warszawska
J. Zachara
Politechnika Warszawska
G. Zukowska
Politechnika Warszawska
M. Marczewski
Politechnika Warszawska
G. Schmidt
Arkema France
W. Wieczorek
Politechnika Warszawska
Centre national de la recherche scientifique (CNRS)
Journal of the Electrochemical Society
0013-4651 (ISSN) 1945-7111 (eISSN)
Vol. 167 7 070562Ämneskategorier
Oorganisk kemi
Materialkemi
Annan kemiteknik
Annan fysik
DOI
10.1149/1945-7111/ab829c