Review-Development of Huckel Type Anions: From Molecular Modeling to Industrial Commercialization. A Success Story
Reviewartikel, 2020

This paper reviews the battery electrolyte technologies involving Huckel-type salts as a major electrolyte component. The concept was initially proposed by M. Armand in 1995 and then explored by several research groups. In the present review studies on the optimization of the electrolyte composition starting from molecular modeling through enhancing the yield of the salt synthesis to structural characterization and electrochemical performance are described. Furthermore, the use of the optimized electrolytes in a variety of lithium-ion and post-lithium batteries is presented and discussed. Finally, the commercialization of the up to date technology by Arkema is discussed as well as the performance of the present Huckel anion based electrolytes as compared to other marketed electrolyte technologies.

Författare

M. Armand

CIC EnergiGUNE

Patrik Johansson

Chalmers, Fysik, Kondenserade materiens fysik

M. Bukowska

Politechnika Warszawska

P. Szczecinski

Politechnika Warszawska

L. Niedzicki

Centre national de la recherche scientifique (CNRS)

Politechnika Warszawska

M. Marcinek

Politechnika Warszawska

Centre national de la recherche scientifique (CNRS)

M. Dranka

Politechnika Warszawska

J. Zachara

Politechnika Warszawska

G. Zukowska

Politechnika Warszawska

M. Marczewski

Politechnika Warszawska

G. Schmidt

Arkema CRRA

W. Wieczorek

Centre national de la recherche scientifique (CNRS)

Politechnika Warszawska

Journal of the Electrochemical Society

0013-4651 (ISSN)

Vol. 167 7 070562

Ämneskategorier

Oorganisk kemi

Materialkemi

Annan kemiteknik

DOI

10.1149/1945-7111/ab829c

Mer information

Senast uppdaterat

2020-06-11