Large easy-axis anisotropy in the one-dimensional magnet BaMo(PO4)(2)
Artikel i vetenskaplig tidskrift, 2019
We present an extensive experimental and theoretical study on the low-temperature magnetic properties of the monoclinic anhydrous alum compound BaMo(PO4)(2). The magnetic susceptibility reveals strong antiferromagnetic interactions theta(CW) = -167 K and long-range magnetic order at T-N = 22 K, in agreement with a recent report. Powder neutron diffraction furthermore shows that the order is collinear, with the moments near the ac plane. Neutron spectroscopy reveals a large excitation gap Delta = 15 meV in the low-temperature ordered phase, suggesting a much larger easy-axis spin anisotropy than anticipated. However, the large anisotropy justifies the relatively high ordered moment, Neel temperature, and collinear order observed experimentally and is furthermore reproduced in a first-principles calculations by using a new computational scheme. We therefore propose BaMo(PO4)(2) to host S = 1 antiferromagnetic chains with large easy-axis anisotropy, which has been theoretically predicted to realize novel excitation continua.
Författare
Aly Abdeldaim
Chalmers, Kemi och kemiteknik, Energi och material, Oorganisk miljökemi
University of Liverpool
ISIS Facility
Danis Badrtdinov
ISIS Facility
Alexandra S. Gibbs
Science and Technology Facilities Council (STFC)
Pascal Manuel
Science and Technology Facilities Council (STFC)
Helen C. Walker
Science and Technology Facilities Council (STFC)
Manh Duc Le
Science and Technology Facilities Council (STFC)
Chien Hung Wu
Science and Technology Facilities Council (STFC)
Dariusz Wojciech Wardecki
Chalmers, Kemi och kemiteknik, Energi och material, Oorganisk miljökemi 2
Sten Eriksson
Chalmers, Kemi och kemiteknik, Energi och material, Oorganisk miljökemi 2
Yaroslav O. Kvashnin
Uppsala universitet
Alexander A. Tsirlin
Ural Federal University
Universität Augsburg
Goran J. Nilsen
Science and Technology Facilities Council (STFC)
Physical Review B
24699950 (ISSN) 24699969 (eISSN)
Vol. 100 21 214427Ämneskategorier
Oorganisk kemi
Teoretisk kemi
Den kondenserade materiens fysik
DOI
10.1103/PhysRevB.100.214427