Chip-scale solar thermal electrical power generation
Artikel i vetenskaplig tidskrift, 2022

There is an urgent need for alternative compact technologies that can derive and store energy from the sun, especially the large amount of solar heat that is not effectively used for power generation. Here, we report a combination of solution- and neat-film-based molecular solar thermal (MOST) systems, where solar energy can be stored as chemical energy and released as heat, with microfabricated thermoelectric generators to produce electricity when solar radiation is not available. The photophysical properties of two MOST couples are characterized both in liquid with a catalytical cycling setup and in a phase-interconvertible neat film. Their suitable photophysical properties let us combine them individually with a microelectromechanical ultrathin thermoelectric chip to use the stored solar energy for electrical power generation. The generator can produce, as a proof of concept, a power output of up to 0.1 nW (power output per unit volume up to 1.3 W m−3). Our results demonstrate that such a molecular thermal power generation system has a high potential to store and transfer solar power into electricity and is thus potentially independent of geographical restrictions.

Författare

Zhihang Wang

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Zhenhua Wu

Shanghai Jiao Tong University

Zhiyu Hu

Shanghai Jiao Tong University

Jessica Orrego Hernandez

Teknisk ytkemi

Erzhen Mu

Henan Polytechnic University

Zhao Yang Zhang

Shanghai Key Lab of Electrical Insulation & Thermal Aging

Martyn Jevric

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Yang Liu

Shanghai Jiao Tong University

Xuecheng Fu

Shanghai Jiao Tong University

Fengdan Wang

Shanghai Jiao Tong University

Tao Li

Shanghai Key Lab of Electrical Insulation & Thermal Aging

Kasper Moth-Poulsen

Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)

Institucio Catalana de Recerca i Estudis Avancats

Chalmers, Kemi och kemiteknik, Tillämpad kemi

Cell Reports Physical Science

26663864 (eISSN)

Vol. 3 3 100789

Molecular Solar Thermal energy storage systems (MOST)

Europeiska kommissionen (EU) (EC/H2020/951801), 2020-09-01 -- 2024-02-29.

Energimyndigheten (2019-010724), 2019-05-07 -- 2019-09-03.

Ämneskategorier

Energiteknik

Energisystem

Annan elektroteknik och elektronik

DOI

10.1016/j.xcrp.2022.100789

Mer information

Senast uppdaterat

2022-06-09