Regulating the Solvation Structure of Electrolyte via Dual–Salt Combination for Stable Potassium Metal Batteries
Artikel i vetenskaplig tidskrift, 2023

Batteries using potassium metal (K-metal) anode are considered a new type of low-cost and high-energy storage device. However, the thermodynamic instability of the K-metal anode in organic electrolyte solutions causes uncontrolled dendritic growth and parasitic reactions, leading to rapid capacity loss and low Coulombic efficiency of K-metal batteries. Herein, an advanced electrolyte comprising 1 M potassium bis(fluorosulfonyl)imide (KFSI) + 0.05 M potassium hexafluorophosphate (KPF6) dissolved in dimethoxyethane (DME) is introduced as a simple and effective strategy of regulated solvation chemistry, showing an enhanced interfacial stability of the K-metal anode. Incorporating 0.05 M KPF6 into the 1 M KFSI in DME electrolyte solution decreases the number of solvent molecules surrounding the K ion and simultaneously leads to facile K+ de-solvation. During the electrodeposition process, these unique features can lower the exchange current density between the electrolyte and K-metal anode, thereby improving the uniformity of K electrodeposition, as well as potentially suppressing dendritic growth. Even under a high current density of 4 mA cm−2, the K-metal anode in 0.05 M KPF6-containing electrolyte ensures high areal capacity and an unprecedented lifespan with stable Coulombic efficiency in both symmetrical half-cells and full-cells employing a sulfurized polyacrylonitrile cathode.

phase-field modeling

potassium metal batteries

potassium metal anode

electrolyte modulation

Författare

Jimin Park

Hanyang University

Gwangeon Oh

Hanyang University

Un Hyuck Kim

Hanyang University

Muhammad Hilmy Alfaruqi

Chonnam National University

Xieyu Xu

Xi'an Jiaotong University

Yangyang Liu

Xi'an Jiaotong University

Shizhao Xiong

Chalmers, Fysik, Materialfysik

Adi Tiara Zikri

Chonnam National University

Yang Kook Sun

Hanyang University

Jaekook Kim

Chonnam National University

Jang Yeon Hwang

Hanyang University

Advanced Science

2198-3844 (ISSN) 21983844 (eISSN)

Vol. 10 16 2301201

Ämneskategorier

Oorganisk kemi

Materialkemi

Annan kemiteknik

DOI

10.1002/advs.202301201

PubMed

37068194

Mer information

Senast uppdaterat

2024-03-07