Experimental investigations of ageing of commercial BEV Li-ion batteries
Licentiatavhandling, 2023
In the compiled works, results from extensive testing on discharge current frequency, variation in SOC level and temperature are reported for cells with mixed material negative electrodes (Graphite/ SiOx ). Unexpected trends where cycling in low SOC causes more rapid degradation than cycling in high SOC are observed. The capacity retention after 1200 FCE was 84.7% for cells cycled in 5-15% SOC, whereas for cells cycled in 45-55% SOC the capacity retention after 1200 FCE was 94.7%. This dependency is shown to be stronger than the temperature dependency for mixed material negative electrodes. It is also demonstrated that dynamic current profiles affect the capacity retention with a strong correlation for frequencies below 100 mHz.
The ageing processes involved are analysed using various in situ electrochemical characterisation techniques and post-mortem investigations. The strong SOC dependency is shown to be largely attributed to ageing of SiOx in mixed material electrodes, with LAMSiOx contributing to a loss of 7% of
overall capacity in 5-15% SOC cycling, compared to only 3% in 85-95% SOC cycling. For 0-50% SOC cycling in 45°C temperature, capacity retention of
SiOx had dropped to ∼ 25 % of initial capacity, whereas graphite capacity was still in excess of 90% of initial capacity.
lithium plating
Electric Vehicles
ageing
Physics-based modelling
Lithium Ion Batteries
State of Charge
NCA
silicon oxide
lifetime
Författare
Kristian Bartholdsson Frenander
Chalmers, Elektroteknik, Elkraftteknik
Low Frequency influence on degradation of commercial Li-ion battery
Electrochimica Acta,;Vol. 462(2023)
Artikel i vetenskaplig tidskrift
N. Roy Chowdhury, A.J. Smith, K. Frenander, A. Mikheenkova, R. Wreland Lindström, T. Thiringer, The State of Charge Dependence of Degradation in Lithium-ion Cells From a Tesla Model 3
Ageing of High Energy Density Automotive Li-Ion Batteries: The Effect of Temperature and State-of-Charge
Journal of the Electrochemical Society,;Vol. 170(2023)
Artikel i vetenskaplig tidskrift
Åldringsfenomen kopplade till dynamisk cykling av Li-jon batterier för fordonsapplikation
Energimyndigheten (2018-018491), 2019-08-30 -- 2023-11-30.
Drivkrafter
Hållbar utveckling
Styrkeområden
Transport
Ämneskategorier
Annan kemiteknik
Farkostteknik
Annan elektroteknik och elektronik
Utgivare
Chalmers