Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects
Artikel i vetenskaplig tidskrift, 2023

The current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition, the powders were prepared by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical conductivity, thermal expansion, and sinterability behaviour. Coated steel samples were oxidised in an air atmosphere at 750 °C for 3000 h. In parallel, a state-of-the-art MnCo2O4 spinel oxide was tested as a reference. The coatings and oxide scale microstructures of the surfaces and cross-sections were examined by XRD, and SEM-EDX. TEM-EDX, XRF, and micro-XRD were also performed on the cross-section lamellae. The electrical properties of the steel-coating system were evaluated by Area Specific Resistance measurement. The results confirm that Mn–Cu–Fe oxides exhibit higher conductivity and lower TEC than Mn–Co oxide. Based on the obtained results, it might be concluded that the proposed coatings are a promising alternative to coatings that contain cobalt.

Copper compound

Cobalt compound

X ray diffraction

Thermal expansion

Iron oxides

Författare

Justyna Ignaczak

Politechnika Gdańska

Lunjie Zeng

Chalmers, Fysik, Nano- och biofysik

Dario Ferreira Sanchez

Paul Scherrer Institut

Małgorzata Makowska

Paul Scherrer Institut

Karolina Górnicka

Politechnika Gdańska

Krystian Lankauf

Politechnika Gdańska

Jakub Karczewski

Politechnika Gdańska

Piotr Jasiński

Politechnika Gdańska

Sebastian Molin

Politechnika Gdańska

International Journal of Hydrogen Energy

0360-3199 (ISSN)

Vol. 48 92 36076-36093

Enabling Science and Technology through European Electron Microscopy (ESTEEM3)

Europeiska kommissionen (EU) (EC/H2020/823717), 2019-01-01 -- 2022-12-31.

Ämneskategorier

Oorganisk kemi

Bearbetnings-, yt- och fogningsteknik

Infrastruktur

Chalmers materialanalyslaboratorium

Styrkeområden

Materialvetenskap

DOI

10.1016/j.ijhydene.2023.06.041

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Senast uppdaterat

2024-03-07