Structural Transition with a Sharp Change in the Electrical Resistivity and Spin-Orbit Mott Insulating State in a Rhenium Oxide, Sr3Re2O9
Artikel i vetenskaplig tidskrift, 2021
We report the successful synthesis, crystal structure, and electrical properties of Sr3Re2O9, which contains Re6+ with the 5d1 configuration. This compound is isostructural with Ba3Re2O9 and shows a first-order structural phase transition at ∼370 K. The low-temperature (LT) phase crystallizes in a hettotype structure of Ba3Re2O9, which is different from that of the LT phase of Sr3W2O9, suggesting that the electronic state of Re6+ plays an important role in determining the crystal structure of the LT phase. The structural transition is accompanied by a sharp change in the electrical resistivity. This is likely a metal–insulator transition, as suggested by the electronic band calculation and magnetic susceptibility. In the LT phase, the ReO6 octahedra are rotated in a pseudo-a0a0a+ manner in Glazer notation, which corresponds to C-type orbital ordering. Paramagnetic dipole moments were confirmed to exist in the LT phase by muon spin rotation and relaxation measurements. However, the dipole moments shrink greatly because of the strong spin–orbit coupling in the Re ions. Thus, the electronic state of the LT phase corresponds to a Mott insulating state with strong spin–orbit interactions at the Re sites.
Crystal structure
Physical and chemical processes
Ions
Phase transitions
Oxides
Författare
Daisuke Urushihara
Nagoya Institute of Technology
Toru Asaka
Nagoya Institute of Technology
Koichiro Fukuda
Nagoya Institute of Technology
Masanobu Nakayama
Nagoya Institute of Technology
Kyoto University
National Institute for Materials Science (NIMS)
Yuki Nakahira
Hiroshima University
Chikako Moriyoshi
Hiroshima University
Yoshihiro Kuroiwa
Hiroshima University
Ola Kenji Forslund
Kungliga Tekniska Högskolan (KTH)
Nami Matsubara
Kungliga Tekniska Högskolan (KTH)
Martin Mansson
Kungliga Tekniska Högskolan (KTH)
Konstantinos Papadopoulos
Chalmers, Fysik, Materialfysik
Yasmine Sassa
Chalmers, Fysik, Materialfysik
Kazuki Ohishi
Comprehensive Research Organization for Science and Society (CROSS)
Jun Sugiyama
Comprehensive Research Organization for Science and Society (CROSS)
Yoshitaka Matsushita
National Institute for Materials Science (NIMS)
Hiroya Sakurai
National Institute for Materials Science (NIMS)
Inorganic Chemistry
0020-1669 (ISSN) 1520-510X (eISSN)
Vol. 60 2 507-514Ämneskategorier
Oorganisk kemi
Materialkemi
Den kondenserade materiens fysik
Drivkrafter
Hållbar utveckling
Styrkeområden
Materialvetenskap
DOI
10.1021/acs.inorgchem.0c02750