The Role of Rare-Earth Atoms in the Anisotropy and Antiferromagnetic Exchange Coupling at a Hybrid Metal–Organic Interface
Artikel i vetenskaplig tidskrift, 2024
Magnetic anisotropy and magnetic exchange interactions are crucial parameters that characterize the hybrid metal–organic interface, a key component of an organic spintronic device. It is shown that the incorporation of 4f RE atoms to hybrid metal–organic interfaces of CuPc/REAu2 type (RE = Gd, Ho) constitutes a feasible approach toward on-demand magnetic properties and functionalities. The GdAu2 and HoAu2 substrates differ in their magnetic anisotropy behavior. Remarkably, the HoAu2 surface promotes the inherent out-of-plane anisotropy of CuPc, owing to the match between the anisotropy axis of substrate and molecule. Furthermore, the presence of RE atoms leads to a spontaneous antiferromagnetic exchange coupling at the interface, induced by the 3d–4f superexchange interaction between the unpaired 3d electron of CuPc and the 4f electrons of the RE atoms. It is shown that 4f RE atoms with unquenched quantum orbital momentum ((Formula presented.)), as it is the case of Ho, induce an anisotropic interfacial exchange coupling.
hybrid metal-organic interfaces
magnetic anisotropy
rare-earths
AFM exchange coupling
X-ray magnetic circular dichroism spectroscopy
Författare
M. Blanco-Rey
Consejo Superior de Investigaciones Científicas (CSIC)
Donostia International Physics Center
Universidad del Pais Vasco / Euskal Herriko Unibertsitatea
Rodrigo Castrillo
Donostia International Physics Center
Consejo Superior de Investigaciones Científicas (CSIC)
Khadiza Ali
Consejo Superior de Investigaciones Científicas (CSIC)
Donostia International Physics Center
Chalmers, Mikroteknologi och nanovetenskap, Kvantkomponentfysik
Pierluigi Gargiani
El Sincrotrón ALBA
M. Ilyn
Consejo Superior de Investigaciones Científicas (CSIC)
Michele Gastaldo
Czech Academy of Sciences
Institut Catala de Nanociencia i Nanotecnologia
Markos Paradinas
Consejo Superior de Investigaciones Científicas (CSIC)
Institut Catala de Nanociencia i Nanotecnologia
Miguel A. Valbuena
IMDEA Nanoscience Institute
Institut Catala de Nanociencia i Nanotecnologia
Aitor Mugarza
Institut Catala de Nanociencia i Nanotecnologia
Institucio Catalana de Recerca i Estudis Avancats
J. Enrique Ortega
Universidad del Pais Vasco / Euskal Herriko Unibertsitatea
Consejo Superior de Investigaciones Científicas (CSIC)
Donostia International Physics Center
F. Schiller
Consejo Superior de Investigaciones Científicas (CSIC)
L. Fernandez
CIC nanoGUNE
Consejo Superior de Investigaciones Científicas (CSIC)
Small
1613-6810 (ISSN) 1613-6829 (eISSN)
Vol. 20 45 2402328Ämneskategorier (SSIF 2011)
Den kondenserade materiens fysik
DOI
10.1002/smll.202402328