MXenes: Multifunctional 2D materials for hydrogen evolution, energy storage, and carbon capture applications
Artikel i vetenskaplig tidskrift, 2025
Ti₃C₂Tₓ MXene was synthesized by selective etching of Ti₃AlC₂ MAX phase using HF. Structural and surface properties were assessed via XRD, Raman, SEM, HRTEM, BET, and XPS, confirming Al removal, interlayer expansion, and functionalization with [sbnd]F, –OH, and = O groups. The resulting MXene exhibited a specific surface area of 26.7 m2/g and pore size of 16.2 nm. A single batch was deployed in three applications: as an HER electrocatalyst in 1 M H₂SO₄, achieving −511 mV onset potential, 190 mA cm−2 at −760 mV, and a Tafel slope of 184 mV dec−1; as a supercapacitor electrode in 3 M KOH, with areal capacitance of 411.1 mF cm−2 and 86.9 % diffusion-controlled contribution; as a CO₂ adsorbent, achieving uptakes of 0.80 and 0.66 mmol g−1 at 0 °C and 25 °C, respectively. Adsorption data fitted best to the Radke–Prausnitz isotherm, indicating mixed physisorption–chemisorption. A techno-economic analysis yielded a production cost of ~2.83 €/g. These results demonstrate the multifunctionality and scalability of Ti₃C₂Tₓ MXene as a good material for hydrogen generation, energy storage, and carbon capture.
MAX phase
Supercapacitor
CO2 adsorption
Ti3C2Tₓ
HER reaction
MXene
Författare
Jarosław Serafin
Universitat de Barcelona
Institut de Nanociencia i Nanotecnologia
Stefanos Chaitoglou
Universitat de Barcelona
Institut de Nanociencia i Nanotecnologia
Ghulam Farid
Institut de Nanociencia i Nanotecnologia
Universitat de Barcelona
Yang Ma
Universitat de Barcelona
Institut de Nanociencia i Nanotecnologia
Bartosz Dziejarski
Chalmers, Rymd-, geo- och miljövetenskap, Energiteknik
Politechnika Wrocławska
Adria Sanchez
Universitat de Barcelona
Xavier Vendrell
Universitat de Barcelona
Roger Amade-Rovira
Universitat de Barcelona
Institut de Nanociencia i Nanotecnologia
Chemical Engineering Journal
13858947 (ISSN)
Vol. 523 168650Ämneskategorier (SSIF 2025)
Materialkemi
Den kondenserade materiens fysik
DOI
10.1016/j.cej.2025.168650