Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies
Artikel i vetenskaplig tidskrift, 2008

Hydrothermal technologies are broadly defined as chemical and physical transformations in high-temperature (200–600° C), high-pressure (5–40 MPa) liquid or supercritical water. This thermochemical means of reforming biomass may have energetic advantages, since, when water is heated at high pressures a phase change to steam is avoided which avoids large enthalpic energy penalties. Biological chemicals undergo a range of reactions, including dehydration and decarboxylation reactions, which are influenced by the emperature, pressure, concentration, and presence of homogeneous or heterogeneous catalysts. Several biomass hydrothermal conversion processes are in development or demonstration. Liquefaction processes are generally lower temperature (200–400° C) reactions which produce liquid products, often called ‘‘bio-oil’’ or ‘‘bio-crude’’. Gasification processes generally take place at higher temperatures (400–700° C) and can produce methane or hydrogen gases in high yields.

Författare

Andrew A. Peterson

Massachusetts Institute of Technology (MIT)

Paul Scherrer Institut

Frederic Vogel

Paul Scherrer Institut

Morgan Fröling

Chalmers, Kemi- och bioteknik, Kemisk miljövetenskap

Morgan Fröling

Chalmers University of Technology

Russell P Lachance

University of Hawaii at Manoa School of Ocean and Earth Science and Technology

Jefferson W. Tester

Massachusetts Institute of Technology (MIT)

Energy and Environmental Sciences

1754-5692 (ISSN)

Vol. 1 1 32-65

Ämneskategorier

Energiteknik

Kemiska processer

Annan naturresursteknik

Kemi

DOI

10.1039/b810100k