Dimeric (isoquinoline)(N-salicylidene-D,L-glutamato)copper(II) ethanol solvate
Artikel i vetenskaplig tidskrift, 2009

The title racemic complex, bis[μ-N-(2-oxidobenzylidene)-D,L-glutamato(2-)]bis[(isoquinoline)copper(II)] ethanol disolvate, [Cu2(C12H11NO5)2(C9H7N)2]·2C2H6O, adopts a square-pyramidal CuII coordination mode with a tridentate N-salicylideneglutamato Schiff base dianion and an isoquinoline ligand bound in the basal plane. The apex of the pyramid is occupied by a phenolic O atom from the adjacent chelate molecule at an apical distance of 2.487(3) Å, building a dimer located on the crystallographic inversion center. The Cu...Cu spacing within the dimers is 3.3264(12) Å. The ethanol solvent molecules are hydrogen bonded to the dimeric complex molecules, forming infinite chains in the a direction. The biological activity of the title complex has been studied.

x-ray structure

Schiff base complex

Författare

Vratislav Langer

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

Dalma Gyepesová

Slovak Academy of Sciences

Maria Kohutova

Univerzita Komenskeho v Bratislave

Aladar Valent

Univerzita Komenskeho v Bratislave

Acta Crystallographica Section C: Crystal Structure Communications

0108-2701 (ISSN) 1600-5759 (eISSN)

Vol. C65 5 m208-m210

Ämneskategorier

Oorganisk kemi

Strukturbiologi

DOI

10.1107/S0108270109009731

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Senast uppdaterat

2018-03-19