Total spontaneous resolution of five-coordinate complexes.
Artikel i vetenskaplig tidskrift, 2009
Talking about a resolution: Bulk quantities of five-coordinate complexes have been resolved for the first time using zinc and cadmium diethyldithiocarbamate species. The stereochemical outcome can be controlled by seeding with the desired isomer, giving access to either enantiomer in high enantiomeric excess and yield.
asymmetric synthesis • chiral resolution • circular dichroism • five-coordinate complexes • structure elucidation