Total spontaneous resolution of five-coordinate complexes.
Artikel i vetenskaplig tidskrift, 2009

Talking about a resolution: Bulk quantities of five-coordinate complexes have been resolved for the first time using zinc and cadmium diethyldithiocarbamate species. The stereochemical outcome can be controlled by seeding with the desired isomer, giving access to either enantiomer in high enantiomeric excess and yield.

asymmetric synthesis • chiral resolution • circular dichroism • five-coordinate complexes • structure elucidation

Författare

Anders Lennartsson

Göteborgs universitet

Mikael Håkansson

Göteborgs universitet

Angewandte Chemie - International Edition

1433-7851 (ISSN) 1521-3773 (eISSN)

Vol. 48 5869-71

Ämneskategorier

Kemi

DOI

10.1002/anie.200902206

PubMed

19582750