Interzeolite Conversion of FAU Type Zeolite into CHA and its Application in NH3-SCR
Artikel i vetenskaplig tidskrift, 2013
In this work we studied the potential feasibility to synthesize small pore zeolites, such as chabazite (CHA) via interzeolite conversion of FAU type zeolite. We have thereafter used CHA as the starting material to obtain Cu-CHA. When CHA in NH4 (+) form was used to prepare Cu-CHA, the large size of the potassium cation present in the structure caused pore blockage in the chabazite framework, and diminished the adsorption and exchange capacity. However, Cu-CHA with comparable Selective Catalytic Reduction performance to the commercial catalyst was obtained via ion exchange if Cu-exchange was performed from H+-CHA form. Still, the main challenge was to fully eliminate K+ from the zeolite structure in order to further improve its catalytic performance and high temperature stability.
scr
Zeolite synthesis
nox
performance
selective catalytic-reduction
Cu-CHA
NH3-SCR
nitric-oxide
ammonia
potassium chabazite
decomposition
NH3 oxidation
encapsulation
hydrothermal stability
Författare
Radka Nedyalkova
Kompetenscentrum katalys
Chalmers, Kemi- och bioteknik, Kemisk reaktionsteknik
C. Montreuil
Ford Motor Company
C. Lambert
Ford Motor Company
Louise Olsson
Chalmers, Kemi- och bioteknik, Kemisk reaktionsteknik
Kompetenscentrum katalys
Topics in Catalysis
1022-5528 (ISSN) 1572-9028 (eISSN)
Vol. 56 9-10 550-557Styrkeområden
Transport
Ämneskategorier
Kemiska processer
Kemi
DOI
10.1007/s11244-013-0015-4