Structural Raman Enhancement in Graphite Nano-Discs
Paper i proceeding, 2016

Raman scattering in disc-shaped graphite nanostructures, etched out of bulk HOPG, are investigated using an excitation wavelength of 532 nm at different laser power. The G-band is fitted using two Lorentzian functions, G(L) and G(H). The difference of Raman shift between the two Lorentzian functions increase with laser power as a consequence of selective absorption and heating of the discs. Further, the G-band from the nanostructured HOPG reveal a Raman enhancement (R-E) of similar to 2.2 and similar to 1.5 for the components associated with the discs (G(L)) and the supporting substrate (G(H)), respectively. The quantitative agreement between the experimental results and performed finite difference time domain calculations make possible to conclude that electromagnetic energy penetrates considerably into the discs from the circular periphery probably due to multiple scattering. In addition, the dependence of R-E of the G(L) component on the laser power is attributed to a temperature dependent electron-phonon coupling.

Författare

[Person 47f9f8de-c9df-4e52-a64c-6da5354f4652 not found]

Escuela Politécnica Nacional

Universitetet i Oslo

[Person ee3d4fdb-233b-4e9f-9e7c-fa38a005d37c not found]

Chalmers, Fysik, Kemisk fysik

[Person e5d1911a-0b79-4384-9613-4a5034ee4ba8 not found]

Chalmers, Fysik, Kemisk fysik

Proceedings of SPIE - The International Society for Optical Engineering

0277786X (ISSN) 1996756X (eISSN)

Vol. 9883 Article Number: 98830L- 98830L
978-1-5106-0128-4 (ISBN)

Ämneskategorier

Atom- och molekylfysik och optik

DOI

10.1117/12.2231084

ISBN

978-1-5106-0128-4

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Senast uppdaterat

2018-05-08