Natural abundance solid-state S-33 NMR study of NbS3: applications for battery conversion electrodes
Artikel i vetenskaplig tidskrift, 2019

We report ultra-wideline, high-field natural abundance solid-state S-33 NMR spectra of the Li-ion battery conversion electrode NbS3, the first S-33 NMR study of a compound containing disulfide (S-2(2-)) units. The large quadrupolar coupling parameters (C-Q approximate to 31 MHz) are consistent with values obtained from DFT calculations, and the spectra provide evidence for the linear Peierls distortion that doubles the number of S-33 sites.


David M. Halat

University of California at Berkeley

University of Cambridge

Sylvia Britto

Diamond Light Source

University of Cambridge

Kent J. Griffith

University of Cambridge

Northwestern University

Erlendur Jonsson

Chalmers, Fysik, Materialfysik

Clare P. Grey

University of Cambridge

Chemical Communications

1359-7345 (ISSN) 1364-548X (eISSN)

Vol. 55 84 12687-12690


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