Microscale fracture of chromia scales
Journal article, 2019

Native protective oxide scales offer resistance against corrosion for high temperature materials, which often work in extreme conditions of varying mechanical and thermal loads. The integrity of such layers is of critical importance, since their damage can lead to significant reduction in material life. Mechanical data such as fracture strain and elastic modulus are required to include oxides in material life estimation models for high temperature materials, but there is lack of such data. Their thickness is in the mm range, which makes mechanical testing for property determination difficult. Here we present a micro-mechanical testing method, based on bending of micro-cantilevers produced by focused ion beam milling, capable of circumventing the limitations of conventional approaches. We apply this method to chromia thermally grown on pure chromium, and measure fracture strains at room and high temperatures (600 °C). The measured fracture strains were found to be higher at room temperature, due to a larger fraction of transgranular fracture. Surprisingly, a large fraction of transgranular fracture was seen even in the presence of stress concentrations at grain boundaries. Removal of the stress concentrations accentuated the propensity for transgranular cracking at room temperature. Realistic values of room temperature elastic modulus were obtained as well. The observed mixed trans- and intergranular cracking points towards the need for dedicated investigations of both oxide grain boundary strength and cleavage resistance of single crystals in order to fully understand the failure mechanisms in thermally grown oxide scales.


electron microscopy



fracture mechanisms


Anand Harihara Subramonia Iyer

Chalmers, Physics, Microstructure Physics

Gaurav Mohanty

Swiss Federal Laboratories for Materials Science and Technology (Empa)

University of Tampere

Krystyna Marta Stiller

Chalmers, Physics, Microstructure Physics

Johann Michler

Swiss Federal Laboratories for Materials Science and Technology (Empa)

Magnus Hörnqvist Colliander

Chalmers, Physics, Microstructure Physics


25891529 (eISSN)

Vol. 8 100465

In-situ micromechanical testing of interfaces for multiscale modeling of fracture

Swedish Research Council (VR) (2015-04719), 2016-01-01 -- 2019-12-31.

Subject Categories

Materials Engineering

Applied Mechanics


Metallurgy and Metallic Materials


Chalmers Materials Analysis Laboratory

Areas of Advance

Materials Science



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