Hot-mould foaming of modified hemicelluloses and hydroxypropyl methylcellulose
Journal article, 2019

Plastics are a material group which have revolutionized the materials industry during the past century. However, the often fossil origin and littering of the material is problematic. Therefore, this study aims at exploring natural polymers, such as cellulose derivatives and hemicelluloses from different botanical origins, and demonstrate the possibility to use these polymers in a foaming application. The hemicelluloses were chemically treated in order to enhance their performance and foams with ratios as high as 4:1 of hemicellulose and the cellulose derivative, respectively, were successfully produced by a hot-mould foaming technique. The foams were found to be thermally stable up to about 280 degrees C. The chemical modifications were confirmed by Fourier transform infrared (FTIR) spectra and the foams were evaluated with regard to their liquid absorption capacity as well as their density. After 1 min the best foam absorbed 12.5 g/g of liquid and after 30 min soak time and centrifugation the foams had absorption capacities between 2 and 5 g/g. All foams exhibited densities below 0.1 g/cm(3). In both the absorption test and density evaluation, the foams produced from mainly hemicellulose performed in a similar way as the reference foams based only on the cellulose derivative, which is considered an impressive result since cellulose is often reported to have superior properties to hemicelluloses.

Liquid absorption

Foaming

Arabinoxylan

Hemicelluloses

Xylan

Hydroxypropyl methylcellulose (HPMC)

Author

Kristina Karlsson

Chalmers, Industrial and Materials Science, Engineering Materials

Filip Nylander

Chalmers, Chemistry and Chemical Engineering, Chemistry and Biochemistry, Physical Chemistry

Malin Lundman

Essity Hyg & Hlth AB

Marco Berta

RISE Research Institutes of Sweden

Mats Stading

Chalmers, Industrial and Materials Science, Engineering Materials

Gunnar Westman

Chalmers, Chemistry and Chemical Engineering, Chemistry and Biochemistry

Mikael Rigdahl

Chalmers, Industrial and Materials Science, Engineering Materials

Journal of Polymer Research

1022-9760 (ISSN) 1572-8935 (eISSN)

Vol. 26 8 206

Subject Categories

Polymer Chemistry

Polymer Technologies

Composite Science and Engineering

DOI

10.1007/s10965-019-1867-5

More information

Latest update

11/11/2019