Hybrid solar energy device for simultaneous electric power generation and molecular solar thermal energy storage
Journal article, 2024

The performance of photovoltaic (PV) solar cells can be adversely affected by the heat generated from solar irradiation. To address this issue, a hybrid device featuring a solar energy storage and cooling layer integrated with a silicon-based PV cell has been developed. This layer employs a molecular solar thermal (MOST) energy storage system to convert and store high-energy photons—typically underutilized by solar cells due to thermalization losses—into chemical energy. Simultaneously, it effectively cools the PV cell through both optical effects and thermal conductivity. Herein, it was demonstrated that up to 2.3% of solar energy could be stored as chemical energy. Additionally, the integration of the MOST system with the PV cell resulted in a notable decrease in the cell's surface temperature by approximately 8°C under standard solar irradiation conditions. The hybrid system demonstrated a solar utilization efficiency of 14.9%, underscoring its potential to achieve even greater efficiencies in forthcoming advanced hybrid PV solar energy systems.

molecular solar thermal energy storage

photovoltaics

solar energy conversion

solar energy storage

Author

Zhihang Wang

University of Cambridge

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry

Helen Hölzel

Polytechnic University of Catalonia

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry

Lorette Fernandez

Institute of Material Science of Barcelona (ICMAB)

Muhammad Adil Salman Aslam

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry

Paulius Baronas

Institute of Material Science of Barcelona (ICMAB)

Jessica Orrego Hernandez

Applied Surface Chemistry

Shima Ghasemi

Chalmers, Chemistry and Chemical Engineering, Chemistry and Biochemistry

M. Campoy-Quiles

Institute of Material Science of Barcelona (ICMAB)

Kasper Moth-Poulsen

Catalan Institution for Research and Advanced Studies

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry

Polytechnic University of Catalonia

Institute of Material Science of Barcelona (ICMAB)

Joule

25424351 (eISSN)

Vol. In Press

Photo Thermal Management Materials (PHOTERM)

European Commission (EC) (EC/H2020/101002131), 2021-10-01 -- 2026-09-30.

Molecular Solar Thermal energy storage systems (MOST)

Swedish Energy Agency (2019-010724), 2019-05-07 -- 2019-09-03.

European Commission (EC) (EC/H2020/951801), 2020-09-01 -- 2024-02-29.

Driving Forces

Sustainable development

Subject Categories

Energy Engineering

Energy Systems

Areas of Advance

Energy

DOI

10.1016/j.joule.2024.06.012

More information

Latest update

8/7/2024 9