Mechanistic Study of Lean NO2 Reduction by Propane Over HZSM-5 in the Presence of Water
Artikel i vetenskaplig tidskrift, 2006

This study focuses on the mechanism of lean NO2 redn. by propane in the presence of water, over an acidic zeolite (HZSM-5). Fourier Transform IR spectroscopy measurements with NO2 and propane in excess oxygen show formation of surface bound NO+, isocyanate, unsatd. hydrocarbons and traces of amine species. Upon addn. of water the isocyanate species disappear and amine species are formed. Hence, it seems likely that the isocyanate species are hydrolyzed to amine species, which are possible reaction intermediates in the HC-SCR reaction over HZSM-5.

HZSM-5

Propane

Lean NOx reduction

FTIR

Författare

Hanna Härelind

Kompetenscentrum katalys (KCK)

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

Magnus Skoglundh

Kompetenscentrum katalys (KCK)

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

Catalysis Letters

1011-372X (ISSN) 1572-879X (eISSN)

Vol. 106 1-2 15-19

Drivkrafter

Hållbar utveckling

Styrkeområden

Nanovetenskap och nanoteknik

Transport

Energi

Materialvetenskap

Ämneskategorier

Kemiteknik

Miljövetenskap

DOI

10.1007/s10562-005-9184-5

Mer information

Skapat

2017-10-07