Anionic zinc-trimesic acid MOFs with unusual topologies: Reversible hydration studies
Artikel i vetenskaplig tidskrift, 2010

The reaction of 1,3,5-benzenetricarboxylic acid (H3BTC) with ZnSO4 center dot 6H(2)O in a DMF-water solution afforded two new metal-organic frameworks [Zn-6(mu(3)-OH)(2)(BTC)(4)(DMF)(2.5)(H2O)(2)]center dot[Zn(H2O)(3)(DMF)(3)]center dot 3.1H(2)O (1) and Zn-2(HBTC)(BTC)(H2O)(3)]center dot DMA center dot 3H(2)O (2). Both compounds are thermally stable and can be prepared reproducibly. Rehydration experiments on compound 2 demonstrate reversible dehydration and rehydration while 1 rehydrates to a different crystalline material. Network analysis revealed a binodal (3,6)-net for 1 and a (3,5)-net for 2, both rare topologies.

porous

metal-organic frameworks

ligand

network

water

material

single-crystal

design

coordination polymer

dehydration

building units

Författare

K. Davies

University of Cape Town

S. A. Bourne

University of Cape Town

Lars Öhrström

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

C. L. Oliver

University of Cape Town

Dalton Transactions

1477-9226 (ISSN) 1477-9234 (eISSN)

Vol. 39 2869-2874

Ämneskategorier

Kemi

DOI

10.1039/b922690g