Transition metal complexes with (NO)(3)(-) anions
Artikel i vetenskaplig tidskrift, 1999

Density functional theory calculations are performed to determine structures, stabilities, and characteristic vibrational frequencies for metal complexes with nitric oxide trimer ligands. The study emphasizes the possible crucial importance of the 3.0 eV first ionization energy of the (NO)3− anion. Metal complexes with the composition M[(NO)3]2 are considered, where M is Mg, Ni, Cu, and Zn. Properties of the Cu(NO)3 complex are evaluated for reference. Possible technological importance to catalysis and drug delivery systems is implied.

Författare

Itai Panas

Chalmers, Institutionen för oorganisk miljökemi

Anders Snis

Filip Acke

J.R.T Johnson

Chemical Physics Letters

0009-2614 (ISSN)

Vol. 302 431-436

Ämneskategorier

Oorganisk kemi

Teoretisk kemi