Neutron diffraction study of the monoclinic to tetragonal structural transition in LaNbO4 and its relation to proton mobility
Artikel i vetenskaplig tidskrift, 2012

The fergusonite-scheelite structural transition of LaNbO4 was characterized by high-intensity variable temperature neutron powder diffraction in an effort to link structural changes to proton transport in the low temperature monoclinic and high temperature tetragonal polymorphs. The pronounced decrease in enthalpy of proton mobility with increasing temperature in monoclinic LaNbO4, identified by Field et al. [1], was found to coincide with the decrease in a key inter-tetrahedral oxygen separation. At temperatures above the transition, this oxygen to oxygen distance remains constant, behavior that is consistent with the invariant nature of the calculated enthalpy of mobility for the tetragonal phase. This oxygen separation is therefore proposed as the key structural parameter determining the success rate of proton transfer and ultimately the proton diffusion in LaNbO4. Infrared measurements performed on acceptor-doped LaNbO4 show an absorption in the region 2500 to 3700 cm(-1) attributed to the O-H stretching motion influenced by hydrogen bonding.

domain boundary

Fuel cell electrolytes

phase-transitions

Proton conductors

oxides

transformation

conduction

Structural phase transition

niobates

rare-earth orthoniobate

Neutron diffraction

solubility

Författare

M. Huse

Universitetet i Oslo

A. W. B. Skilbred

Universitetet i Oslo

Maths Karlsson

Chalmers, Teknisk fysik, Kondenserade materiens fysik

Sten Eriksson

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

T. Norby

Universitetet i Oslo

R. Haugsrud

Universitetet i Oslo

Christopher Knee

Göteborgs universitet

Journal of Solid State Chemistry

0022-4596 (ISSN) 1095-726X (eISSN)

Vol. 187 27-34

Ämneskategorier

Kemi

DOI

10.1016/j.jssc.2011.12.025