Influence of hydrothermal ageing on NH3-SCR over Fe-BEA -Inhibition of NH3-SCR by ammonia
Paper i proceeding, 2013

The decay in ammonia adsorption capacity and the amount of active iron sites are important to consider in order to understand the deactivation processes of Fe-BEA as NH3-SCR catalyst. NH3 and NO storage capacity experiments together with kinetic modeling have been used to evaluate ammonia inhibition during NH3-SCR before and after hydrothermal treatment of H-BEA and Fe-BEA. The kinetic model shows that at least four types of acid sites for H-BEA and one additional site for Fe-BEA are required to predict the NH3 desorption well. NH3-TPD experiments together with simulations show that the strongest adsorption sites are the sites that are most affected by the hydrothermal treatment. For H-BEA a clear correlation between the ammonia storage capacity and the improved NOX conversion after NH3 cut-off during NH3-SCR is observed. However, Fe-BEA show an inhibiting effect of ammonia after NH3 cut-off but no significant difference (i.e. increased NOX conversion time) between fresh and aged samples can be observed, indicating that the inhibiting effect is unaffected by the hydrothermal treatment.

Ammonia inhibition

Fe-BEA

Dealumination

Ammonia storage

Kinetic modeling

H-BEA

Hydrothermal treatment

Författare

Soran Shwan

Kompetenscentrum katalys

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

Radka Nedyalkova

Kompetenscentrum katalys

Chalmers, Kemi- och bioteknik, Kemisk reaktionsteknik

John G. Korsgren

Volvo Group

Jonas Jansson

Volvo Group

Louise Olsson

Kompetenscentrum katalys

Chalmers, Kemi- och bioteknik, Kemisk reaktionsteknik

Magnus Skoglundh

Chalmers, Kemi- och bioteknik, Teknisk ytkemi

Kompetenscentrum katalys

Topics in Catalysis

1022-5528 (ISSN) 1572-9028 (eISSN)

Vol. 56 1-8 80-88

9th International Congress on Catalysis and Automotive Pollution Control (CAPoC9)
Bryssel, Belgium,

Drivkrafter

Hållbar utveckling

Styrkeområden

Nanovetenskap och nanoteknik (SO 2010-2017, EI 2018-)

Transport

Energi

Materialvetenskap

Ämneskategorier

Kemiska processer

Fundament

Grundläggande vetenskaper

DOI

10.1007/s11244-013-9933-4

Mer information

Senast uppdaterat

2021-07-19